INTRODUCERE ..………………………………………………………………………4
I. CUPRUL IN SISTEME BIOLOGICE………….…………….…………….5
1.1. METODE EXPERIMENTALE DE INVESTIGARE A COMPUSILOR DE Cu(II)
1.1.1. ANALIZA ELEMENTARA.......
1.1.2. SPECTROSCOPIA IN INFRAROŞU...........................................................12
1.1.3. SPECTROSCOPIA IN ULTRAVIOL ET –VIZIBIL.....................................14
1.1.4 REZONANTA ELECTRICA DE SPIN........................................................16
II SINTEZA ŞI CARACTERIZAREA UNOR COMPLECŞI AI Cu(II) CU SULFONAMIDE N-
SUBSTITUITE...........................................18
2.1. SINTEZA SI INVESTIGAREA STRUCTURALA A LIGANDULUI...18
2.1.1. CARACTERIZAREA
LIGANDULUI............................................................18
2.1.2. SPECTROSCOPIE IN
INFRAROSU..............................................................19
2.1.3. SPECTROSCOPIEA ELECTRONICA DE REFLEXIE DIFUZA..................20
2.2. SINTEZA SI INVESTIGAREA STRUCTURALA A COMPLEXUL DE
[CU(L)2]........................................
2.2.1. SPECTROSCOPIE
IR........................................................
2.2.2. SPECTROSCOPIE ELECTRONICA DE REFLEXIE
DIFUZA.....................23
2.2.3. REZONANTA ELECTRONICA DE
SPIN......................................................24
2.3. SINTEZA SI INVESTIGAREA STRUCTURALA A COMPLEXULUI
[Cu(L)2(Py)2]......
2.3.1 SPECTROSCOPIA
IR.
2.3.2 SPECTROSCOPIA ELECTRONICA DE REFLEXI DIFUZA.....................27
2.3.3 REZONANTA ELECTRONICA DE SPIN......................................................28
2.4. COMPLEXUL [Cu(L)2(Cl)2]
2.4.1 SPECTROSCOPIA
IR.....
2.4.2. SPECTROSCOPIA ELECTRONICA DE REFLEXIE DIFUZA...................30
2.4.3 REZONANTA ELECTRONICA D SPIN....................................................31
2.5. FORMULE DE STRUCTURA.............33
III CONCLUZII.......34
BIBLIOGRAFIE..........34